- Card. Víctor Manuel Fernández (from September 2023)
- Card. Luis Francisco Ladaria Ferrer, S.J. (from July 2017 to September 2023)
- Card. Gerhard Ludwig Müller (from July 2012 to June 2017)
- Card. William Joseph Levada (from May 2005 to June 2012)
- Card. Joseph Ratzinger (from November 1981 to April 2005)
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